By Bohuslav Dobias, Hansjoachim Stechemesser
ISBN-10: 1574444557
ISBN-13: 9781574444551
First released in 1993, Coagulation and Flocculation is a pragmatic reference for the researchers within the box of the stabilization and destabilization of excellent good dispersions. by way of omitting chapters that remained unchanged from the 1st variation, the editors of this moment version thoroughly replace, rewrite, and extend upon all chapters to mirror a decade of the most recent advances in either theoretical and alertness facets of the sphere. The authors offer increased fabric that incorporates dissociation from an excellent floor with self sustaining websites; advancements to the Gouy-Chapman version; electric double layer, floor ionization, and floor heterogeneity; skinny liquid motion pictures and modeling of a semi-batch approach utilizing microprocesses chances; and clay mineral intracrystalline reactions, functions, and gelation. New chapters hide homopolymers and their impact on colloid balance, together with by no means earlier than released figures and equations; the soundness of suspensions within the presence of surfactants, polymers, and combinations; and the flocculation and dewatering of fine-particle suspensions, emphasizing floc formation, progress, constitution, and applications.The moment version of Coagulation and Flocculation successfully captures either the theoretical and alertness facets of the newest advances within the evolving box of reliable dispersions, suspensions, and combos.
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Extra info for Coagulation and Flocculation, Second Edition (Surfactant Science)
Example text
G can be calculated from the Gouy–Chapman theory using the relation G¼ 1 ð (cÀ (x) À c)dx, (83) 0 which yields 1 zFw(0) þ 1 þ tgh G ¼ G0 : 2 2 4RT (84) At low interfacial potentials, where the amount of counterion enrichment in the ionic cloud equals that of coion displacement, G is only one-half of G0þ. At high interfacial potentials, however, the enrichment of counterions is much stronger than the displacement of coions (the latter is limited as concentrations cannot become negative). Therefore, in agreement with Equation (84), the ratio G/G0þ approaches 1.
5b. Using for K Equation (38a), we find, with Equation (34), ^u Dhad ¼ A þ m (57b) which should be compared with Equation (48a). Note that m ^, because of Equation (56a), is temperature-independent. ^. C) give qualitatively similar results. Therefore, we omit further discussion of the van der Waals case. E. Surface Tension of Micellar Solutions We include a short discussion of the surface tension of an air– liquid interface of a micellar solution. Assume that a micelle M is formed from n monomers of substance 2.
H. Kohler, Colloid Polym. , 278, 911, 2000. -H. Kohler and S. Woelki Institute of Analytical Chemistry, Chemo- and Biosensors, University of Regensburg, D-93040 Regensburg, Germany I. Introduction .................................................................. 44 II. The Diffuse Double Layer ............................................ 44 A. General Features and Basic Equations of the Gouy–Chapman Model ............................... 44 B. General Solutions..................................................
Coagulation and Flocculation, Second Edition (Surfactant Science) by Bohuslav Dobias, Hansjoachim Stechemesser
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